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September 2012 Volume 1 Issue
6
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Okop IJ
Obadimu CO
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Gobal Advanced Research Journal
of Environmental Science and Toxicology (GARJEST) ISSN:
2315-5140
September 2012 Vol. 1(6), pp.
152-161
Copyright © 2012 Global Advanced Research Journals
Full Length
Research Paper
Quantitative evaluation of the spatial distribution and
penetration of liquid hydrocarbons in petroleum spilled soil
Imeh J. Okop*, Fiokedu S. Okorie and Clement O. Obadimu
Department of Chemistry, Akwa Ibom State University, Mkpat
Enin, P.M.B. 1167, Uyo, Akwa Ibom State, Nigeria.
*Correspondence Author E-mail: imehokop@yahoo.com
Accepted 15 September, 2012
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Abstract |
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Petroleum spillage contamination of soil was
investigated about 38 days after an extensive oil
spillage in South –South Niger Delta. Soil samples
and controls were collected at depths of 0-15 cm,
15-30 cm and 30-60 cm. Samples were analysed using
gas chromatography fitted with a flame ionisation
detector. Penetration and migration of C5-C9,
C10-C26 and C26-C40
hydrocarbons through the soil layers were assessed
to determine the spatial distribution, penetration
and similarity of these compounds over the
contaminated area. The results also indicated
elevated levels of total hydrocarbon contents in the
soil when compared with the reference sites. The
total petroleum hydrocarbon concentrations levels
varied from 9-289 ±3 mg kg-1 topsoil,
11-413±7 mg kg-1 subsoil and 13-178±11 mg
kg-1 at the greatest depth measured. This
paper provides informative guidelines for effective
remediation processes, careful monitoring and the
need to conduct more post-spill studies by competent
remediation professionals.
Keywords:
Petroleum spills, Total Hydrocarbon, soil
contamination, remediation and gas chromatography
fitted with flame ionisation detector (GC-FID).
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